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. 5 B clearly indicates that the change of the band at 1628 cm^sup -1^ was the dominant event at temperatures below 66°C, whereas the asynchronous plot was dominated by noise and no crosspeaks could be identified at a similar position in the synchronous plot
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. Nature 2002; 418:200-203(20) Stuart LM, Ezekowitz RA
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. NOE values were determined from pairs of spectra recorded interleaved with and without a 4-s proton saturation (see Supplementary Materials, Table RS1, for more details)
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. Determining the magnitude of the fully asymmetric diffusion tensor from heteronuclear relaxation data in the absence of structural information
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. Interestingly, the β-sheet content is higher in the A-state than in native TTR, although some loss of contribution from aromatic residues such as Trp also could influence the intensity of the far-UV CD signal (Freskgård et al
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. Gβγ has a propeller-like structure (Wall et al
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. This is particularly relevant to emulsifiers, some of which have a melting point above 150[degrees]F
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. By stabilizing a β-turn that otherwise relies on highly nonlocal, and late-forming, structure for its stability, this temporary helix reduces the dimension of the search space for the nonlocal contacts
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. [infinity] = asymptotic length; k -- Brody growth parameter; [t
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. Journal of Raptor Research 36:58-65
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. Solvent stabilization by salting-out ions is a consequence of a decrease in free energy of the native state, due to both entropic and enthalpic contributions; in particular, the effect on hydration water is expected to be mainly entropic, whereas the observed decrease in protein MSDs (44) indicates a tighter packing of the apolar residues in the core of the protein as suggested for hydrophobic stabilization by calorimetry experiments (59)
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