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. These results indicate a multistate folding pathway for GR and suggest a critical role of molten globule monomers in the correct dimerization of GR
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. The dominant crosspeak in the asynchronous plot was a positive peak centered at (1629 cm^sup -1^, 1617 cm^sup -1^), whereas minor positive peaks could he found at (1648 cm^sup -1^, 1617 cm^sup -1^) and (1658 cm^sup -1^, 1617 cm^sup -1^)
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. In contrast all thermal unfolded states (with the exception of those obtained from PPA) exhibit λ^sub max^ values around 340 nm, which correspond to much smaller red shifts upon unfolding
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. Gα^sub s^ is modified by two palmitoyl chains (Kleuss and Krause, 2003) which are thought to contribute to its membrane stability
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. After 48-h incubation, disk reconstitution is incomplete and a significant amount of lipid-poor apoA-2 is detected (lanes 9 and 10)
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. Arrhenius plots for these phases are linear and intercept near 100°C (Fig
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. Intraresidue entropy differences between the free and complex forms ΔS^sup fir,b-f^^sub mol,all^ (Eq
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. Entropy calculations on a reversibly folding peptide: changes in solute free energy cannot explain folding behavior
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